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12/07/2011 at 3:47 pm #12298AnonymousOnlineTopics: 0Replies: 1150Has thanked: 0 timesBeen thanked: 1 time
Dental amalgam is the most commonly used dental restorative material used for dental fillings. First introduced in France in the early 19th century,it contains a mixture of mercury with at least one other metal. Amalgam has been the restorative method of choice for many years due to its low cost, ease of application, strength, durability, and bacteriostatic effects. Factors that have led to recent decline in use are a lingering concern about detrimental health effects, aesthetics, and environmental pollution. The health issue concerns the known toxic effects of mercury and whether these are present in the amounts released from the amalgam. The aesthetic issue is because the metallic colour does not blend with the natural tooth colour. This is especially a concern when used on front teeth, but it can be addressed using alternative dental materials. The environmental concerns are regarding mercury emissions during preparation and from waste amalgam upon cremation of deceased individuals.
Galvanic shock
When aluminium foil makes contact with some amalgam fillings, saliva in the mouth can act as an electrolyte. This can generate small electrical currents which are felt through the nerves in the tooth as (often extremely painful) electrical “jolts” or shocks.
12/07/2011 at 3:49 pm #17484DrsumitraOfflineRegistered On: 06/10/2011Topics: 238Replies: 542Has thanked: 0 timesBeen thanked: 0 timesGamma 2 phase amalgams
After widespread adoption and wildly varying standards, the multitude of formulas for making amalgams were standardized into the gamma-2-phase amalgam formula in 1895.
The gamma-2-phase amalgams contain approximately equal parts 50% of liquid mercury and 50% of an alloy powder containing:[citation needed] [3]
* > 65% silver (Ag)
* < 29% tin (Sn)
* < 6% copper (Cu)
* < 2% zinc (Zn)
* < 3% mercury (Hg)The resulting amalgam is composed of the gamma phase (the silver-tin eutectic Ag3Sn), which reacts with mercury, yielding the gamma-1 phase (Ag2Hg3) and gamma-2 phase (Sn7-8Hg). The gamma phase is prone to corrosion and its mechanical strength is low. The alloy tends to undergo crevice corrosion and form local galvanic cells, due to the potential difference between the gamma-1 and gamma-2 phases.
Around 1970, the ingredients changed to the new non-gamma-2 form, with lower manufacturing cost, greater mechanical strength, and better corrosion resistance. The reduced-gamma-2 amalgams (sometimes referred to as "high-copper" amalgams [44]) contain approximately equal parts 50% of liquid mercury and 50% of an alloy powder containing:[citation needed]
* > 40% silver (Ag)
* < 32% tin (Sn)
* < 30% copper (Cu)
* < 2% zinc (Zn)
* < 3% mercury (Hg)The amalgam alloy is strengthened by presence of Ag-Cu particles. The gamma-2 phase reacts with the Ag-Cu particles to form eta phase Cu6Sn5 and gamma-1 phase.
The possible difference in toxicology between the two has not been studied conclusively.
12/07/2011 at 3:50 pm #17485DrsumitraOfflineRegistered On: 06/10/2011Topics: 238Replies: 542Has thanked: 0 timesBeen thanked: 0 timesModern use as a dental restoration
Amalgam is an "excellent and versatile restorative material"and is used in dentistry for a number of reasons. It is inexpensive and relatively easy to use and manipulate during placement; it remains soft for a short time so it can be packed to fill any irregular volume, and then forms a hard compound. Amalgam possesses greater longevity when compared to other direct restorative materials, such as composite.However, this difference has decreased with continual development of composite resins.
Amalgam is typically compared to resin-based composites because many applications are similar and many physical properties and costs are comparable.
LongevityAmalgam is "tolerant to a wide range of clinical placement conditions and moderately tolerant to the presence of moisture during placement.[20] In contrast, the techniques for composite resin placement are more sensitive to many factors and require "extreme care"and "considerably greater number of exacting steps".
Mercury has properties of a bacteriostatic agent whereas TEGMA (constituting some older resin-based composites) "encourages the growth of microorganisms.".This leads to increased decay underneath older resin-based composites while those underneath mercury restorations progress much more slowly."
Recurrent marginal decay is a very important factor in restoration failure, but more so in composite restorations. In the Casa Pia study in Portugal (1986–1989), 1,748 posterior restorations were placed and 177 (10.1%) of them failed during the course of the study. Recurrent marginal decay was the main reason for failure in both amalgam and composite restorations, accounting for 66% (32/48) and 88% (113/129), respectively.Polymerization shrinkage, the shrinkage that occurs during the composite curing process, has been implicated as the primary reason for postoperative marginal leakage.
These are some of the reasons why amalgam has remained a superior restorative material over resin-base composites. The New England Children’s Amalgam Trial (NECAT), a randomized controlled trial, yielded results "consistent with previous reports suggesting that the longevity of amalgam is higher than that of resin-based compomer in primary teethand composites in permanent teeth.Compomers were seven times as likely to require replacement and composites were seven times as likely to require repair
There are circumstances in which composite serves better than amalgam. For example, when a more conservative preparation would be beneficial, composite is the recommended restorative material. These situations would include small occlusal restorations, in which amalgam would require the removal of more sound tooth structure,as well as in "enamel sites beyond the height of contour."For cosmetic purposes, composite is preferred when a restoration is required on an immediately visible portion of a tooth.
Removal and replacement of amalgam restorations has traditionally been considered when "ditching" is present on the edges of the restoration. Ditching is "a deficiency of amalgam along the margin, preventing the margin of the cavity preparation from being flush… An area of ditching is also commonly referred to as a submarginal area and it requires removing tooth structure or replacing the amalgam to correct the situation."
13/07/2011 at 5:47 am #17488 -
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